Custom 465 is a titanium-bearing martensitic age-hardenable (precipitation-hardening) stainless steel, premium double-vacuum-melted (VIM + VAR). This datasheet presents the material within the American (ASTM / ASME / AMS / UNS) standard system.
With about 12% chromium, 11% nickel, 1% molybdenum and 1.6% titanium and very low carbon, Custom 465 develops ultra-high strength through precipitation of a nickel-titanium (Ni₃Ti) phase, reaching an ultimate tensile strength above 1724 MPa (250 ksi) in the H950 condition — and approaching 2070 MPa (300 ksi) when cold-worked and aged in small sections — while retaining excellent fracture toughness and corrosion resistance approaching that of type 304. It is supplied solution-annealed for good machinability and forming, then strengthened by a single ageing treatment. It can replace plated high-strength steels such as 300M and AISI 4340, and offers higher strength than 15-5PH, 17-4PH and 13-8Mo.
Typical applications include aerospace structural and landing-gear components, surgical and dental instruments, medical needle wire, and high-strength corrosion-resistant hardware.
Typical values, H1000 condition.
| Property | Value | Unit |
|---|---|---|
| Density | 7.81 | g/cm³ |
| Melting range | 1400–1440 | °C |
| Elastic modulus | 200 | GPa |
| Coefficient of thermal expansion (20–100 °C) | 10.6 | µm/m·°C |
| Thermal conductivity (20 °C) | 14.5 | W/m·K |
| Specific heat (20 °C) | 460 | J/kg·K |
| Structure | Martensitic (precipitation-hardening) | — |
| Element | Symbol | Min % | Max % | Role in Alloy |
|---|---|---|---|---|
| Iron | Fe | Balance | — | Base element |
| Chromium | Cr | 11.0 | 12.5 | Corrosion resistance; martensite former |
| Nickel | Ni | 10.75 | 11.25 | Toughness; Ni₃Ti precipitation |
| Molybdenum | Mo | 0.75 | 1.25 | Strength; pitting resistance |
| Titanium | Ti | 1.50 | 1.80 | Primary precipitation-hardening phase (Ni₃Ti) |
| Manganese | Mn | — | 0.25 | Low (toughness) |
| Silicon | Si | — | 0.25 | Low (toughness) |
| Carbon | C | — | 0.020 | Very low (toughness) |
| Phosphorus | P | — | 0.015 | Very low (toughness) |
| Sulphur | S | — | 0.010 | Very low (toughness) |
Typical values by ageing (H) condition, per ASTM A564 / AMS 5936 for UNS S46500.
| Condition | Tensile strength | 0.2% Yield | Hardness |
|---|---|---|---|
| H900 | ≥1790 MPa (260 ksi) | ≥1690 MPa (245 ksi) | ~51 HRC |
| H950 | ≥1724 MPa (250 ksi) | ≥1620 MPa (235 ksi) | ~50 HRC |
| H1000 | ≥1620 MPa (235 ksi) | ≥1515 MPa (220 ksi) | ~47 HRC |
| Cold-worked + aged (small section) | up to ~2070 MPa (300 ksi) | — | — |
Confirm against the mill test report. H1000 gives the best combination of toughness and stress-corrosion-cracking resistance.
| Environment | Performance | Notes |
|---|---|---|
| Atmospheric / general | Good | Approaches type 304 |
| Mild acids | Moderate | At low concentrations |
| Chloride pitting | Moderate | Molybdenum addition aids resistance |
| Stress-corrosion cracking | Very Good | Best in the H1000 condition |
| Seawater | Limited | Not recommended for prolonged exposure |
General corrosion resistance approaches that of type 304 — markedly better than the low-chromium high-strength steels (300M, 4340) it can replace.
A martensitic precipitation-hardening alloy; supplied solution-annealed and hardened by a single low-temperature ageing treatment.
Solution Treatment Approximately 980 °C, hold, then cool (optionally with a sub-zero/cryogenic step to complete transformation) to form a soft martensitic structure suitable for machining and forming.
Precipitation Hardening (Ageing) A single ageing treatment precipitates Ni₃Ti: H900 (~482 °C) gives maximum strength; H950 gives ~250 ksi UTS; H1000 gives the best toughness and SCC resistance; H1050/H1100 give lower strength with higher ductility. Cold work prior to ageing further raises strength. Air cool after ageing.
Weldable, best in the solution-annealed condition; matching filler is used. Perform post-weld ageing to restore strength; avoid welding in the aged condition (cracking risk).
| Welding Process | Applicability | Filler / Consumable |
|---|---|---|
| GTAW / TIG | Good | Matching Custom 465-type filler |
| GMAW / MIG | Good | Matching filler |
| EBW / laser | Good | Autogenous or matching filler |
Weld in the solution-annealed condition; re-age after welding to restore strength.
Machining Guidelines
| Parameter | Recommendation |
|---|---|
| Preferred condition | Solution-annealed (good machinability and formability) |
| Tooling | Carbide tooling; rigid setup |
| Coolant | Ample flood coolant |
Forming Processes
| Process | Notes |
|---|---|
| Cold forming | Performed in the solution-annealed condition |
| Hot forming | ~1150–950 °C; solution treat + age afterward |
| Industry | Typical Components | Key Requirements |
|---|---|---|
| Aerospace | Landing gear, structural fittings, actuators | Ultra-high strength + fracture toughness |
| Medical | Surgical and dental instruments, needle wire | High strength + corrosion resistance |
| Automotive / motorsport | High-strength shafts, fasteners | Strength-to-weight |
| Defence | High-strength structural components | Strength + corrosion resistance |
| Product Form | ASTM Standard | ASME / AMS |
|---|---|---|
| Bar, wire and forgings | ASTM A564 | ASME SA-564 / AMS 5936 |
| Plate, sheet and strip | ASTM A693 | — |
| Surgical instrument stock | ASTM F899 | — |
| Design data | MMPDS | — |
Titanium-bearing martensitic precipitation-hardening stainless steel. UNS S46500.
| Grade | Cr % | Ni % | Mo % | Other | Best Used For |
|---|---|---|---|---|---|
| Custom 465 | 11–12.5 | 10.75–11.25 | 0.75–1.25 | Ti | Ultra-high-strength PH (>250 ksi); aerospace, medical |
| Custom 455 | 11–12.5 | 7.5–9.5 | — | Cu, Ti, Nb | Ultra-high-strength PH; fabricable |
| 13-8 Mo | 12.25–13.25 | 7.5–8.5 | 2.0–2.5 | Al | Highest-toughness PH; aerospace |
| 15-5PH | 14–15.5 | 3.5–5.5 | — | Cu, Nb | High-strength PH; transverse toughness |
| 17-4PH | 15–17.5 | 3–5 | — | Cu, Nb | General-purpose martensitic PH |




